【材料研究院】吴田《Materials & Design》

发布人：kyzx 发布时间：2019-11-29 浏览次数:368

Substantial doping engineering in Na 3 V 2-x Fe x (PO 4 ) 3 (0≤x≤0.15) as high-rate cathode for sodium-ion battery

Tian Wu; Jianguo Sun; Zu Quan Jeremy Yap; Meilu Ke; Christina Y.H. Lim; Li Lu;

Institute of Materials Research and Engineering, Hubei University of Education, Wuhan, 430205, PR China;

Department of Mechanical Engineering, National University of Singapore, Singapore, 117575, Singapore;

Institute for Functional Materials, Hubei University of Education, Wuhan, 430205, PR China;

National University of Singapore Suzhou Research Institute, Suzhou, 215123, China;

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ABSTRACT:Abstract(#br)Due to its high theoretical capacity and stable structure, Na 3 V 2 (PO 4 ) 3 has gained much attention as a potential cathode for sodium-ion batteries (SIBs) in large-scale energy storage applications. However, poor electronic conductivity usually results in the low rate capacity and poor cyclability, limiting its application. Herein, we successfully introduce Fe 3+ to substitute V 3+ through doping engineering. Compared with Na 3 V 2 (PO 4 ) 3 /C, an excellent initial high-rate ca... 更多

KEYWORDS:NASICON-Structure; Sodium-ion battery; Doping engineering; High-rate performance;

JOURNAL:Materials & Design

SOURCE:Elsevierjournal

DOI:10.1016/j.matdes.2019.108287

YEAR:2020

PUBLISHER:Elsevier Ltd